Wednesday, 18 Sep 2019

OIST improve perovksite solar cells and lower the cost to produce perovskite LEDs

These early developments are an important step towards commercially competitive perovskite soalr cells and perovskite LEDs

17 Aug 2017 | Editor

The Energy Materials and Surface Sciences Unit at OIST led by Prof. Yabing Qi has recently published two scientific papers focusing on the improvement of perovskite solar cells and a cheaper and smarter way to produce emerging perovskite-based LED lights.

The new finding, reported in the Journal of Physical Chemistry B, suggests interactions between components of the solar cell itself are responsible for the rapid degradation of the device.

More precisely, the titanium oxide layer extracting electrons made available through solar energy – effectively creating an electric current – causes unwanted deterioration of the neighbouring perovskite layer.

The researchers provide an analogy - imagine the solar cell as a multi-layered club sandwich: if not properly assembled, fresh and juicy vegetables in contact with the bread slices will make the bread very soggy in a matter of hours. But if you add a layer of ham or turkey between the vegetables and the bread, then your sandwich stays crisp all day in the lunchroom refrigerator.

OIST - A perovskite-based layer includes many layers

Figure: OIST - A perovskite-based layer includes many layers

This is exactly what the OIST researchers achieved: they inserted in the solar cell an additional layer made from a polymer to prevent direct contact between the titanium oxide and the perovskite layers.

This polymer layer is insulating but very thin, which means it lets the electron current tunnel through yet does not diminish the overall efficiency of the solar cell, while efficiently protecting the perovskite structure.

The lifespan of the new perovskite device was extended to over 250 hours - still not enough to compete with commercial photovoltaic cells regarding stability, but an important step forward toward fully functional perovskite solar cells.

The bipolar electronic properties of the perovskite structure not only confer them the ability to generate electricity from solar energy but also can convert electricity into vivid light. Light-Emitting Diode – LED – technology, omnipresent in our daily life from laptop and smartphone screens to car lights and ceiling tubes, currently relies on semi-conductors that are difficult and expensive to manufacture.

Perovskite LEDs are envisaged to become the new industry standard in the near future due to the lower cost and their efficiency to convert power into light. Moreover, by changing the atomic composition in the perovskite structure, perovskite LED can be easily tuned to emit specific colors.

The manufacturing of these perovskite LEDs is currently based on dipping or covering the targeted surface with liquid chemicals, a process which is difficult to setup, limited to small areas and with low consistency between samples.

To overcome this issue, OIST researchers, in collaboration with Prof. Chihaya Adachi and Dr. Chuanjiang Qin from Kyushu University, reported in the Journal of Physical Chemistry Letters the first perovskite LED assembled with gasses, a process called chemical vapour deposition or CVD.

Like the solar cell, the perovskite LED also comprises many layers working in synergy. First, an indium tin oxide glass sheet and a polymer layer allow electrons into the LED. The chemicals required for the perovskite layer – lead bromide and methylammonium bromide - are then successively bound to the sample using CVD, in which the sample is exposed to gasses in order to convert to perovskite instead of typically solution-coating processes with liquid.

In this process, the perovskite layer is composed of nanometer-small grains, whose sizes play a critical role in the efficiency of the device. Finally, the last step involves the deposition of two additional layers and a gold electrode, forming a complete LED structure. The LED can even form specific patterns using lithography during the manufacturing process.

OIST - Perovskite LED

Figure: OIST - Perovskite LED

Controlling the grain size is not the only challenge for this first-of-its-kind assembling technique of LED lights.

The result is a flexible, thick film-like LED with a customisable pattern. The luminance, or brightness, currently reaches 560 cd/m2, while a typical computer screen emits 100 to 1000 cd/m2 and a ceiling fluorescent tube around 12,000 cd/m2.

OIST - Large perovskite-LED produced using chemical vapour deposition

Figure: OIST - Large perovskite-LED produced using chemical vapour deposition

OIST - Researchers from the Energy Materials and Surface Unit at OIST

Figure: OIST - Researchers from the Energy Materials and Surface Unit at OIST

“We added a very thin sheet, only a few nanometers wide, of polystyrene between the perovskite layer and the titanium oxide layer.”

"Electrons can still tunnel cross this new layer and it does not affect the light absorption of the cell. This way, we were able to extend the lifetime of the cell four-fold without loss in energy conversion efficiency”.

Dr. Longbin Qiu

"Chemical vapor deposition is already compatible with the industry, so in principle it would be easy to use this technology to produce LEDs." "The second advantage in using CVD is a much lower variation from batch to batch compared to liquid-based techniques. Finally, the last point is scalability: CVD can achieve a uniform surface over very large areas".

Prof. Yabing Qi

"With large grains, the surface of the LED is rough and less efficient in emitting light. The smaller the grain size, the higher the efficiency and the brighter the light."

"By changing the assembly temperature, we can now control the growth process and the size of the grains for the best efficiency"

"Our next step is to improve the luminance a thousand-fold or more"

"In addition, we have achieved a CVD-based LED emitting green light but we are now trying to repeat the process with different combinations of perovskite to obtain a vivid blue or red light”.

Dr. Lingqiang Meng

"Perovskite is great, but the choice in the adjacent layers is really important too" "To achieve high electricity-to-light conversion rates, every layer should be working in harmony with the others."

Dr. Luis K. Ono


About Okinawa Institute of Science and Technology

The Okinawa Institute of Science and Technology is an interdisciplinary graduate school offering a 5-year PhD program in Science. Over half of the faculty and students are recruited from outside Japan, and all education and research is conducted entirely in English.

Source: Okinawa Institute of Science and Technology

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