Researchers from the University of Surrey's Advanced Technology Institute have recently published the findings in Science Advances which shows how graphene can be manipulated to create the most light-absorbent material for its weight, to date. It is expected that this nanometre-thin material will enable future applications such as "smart wallpaper" that could generate electricity from waste light or heat, and power a host of applications within the growing 'internet of things.
The researchers using a technique known as "nanotexturing", which involves growing graphene around a textured metallic surface, took their inspiration from nature to create ultra-thin graphene sheets designed to more effectively capture light. Just one atom thick, graphene is very strong but traditionally inefficient at light absorption. To combat this, the team used the nano-patterning to localise light into the narrow spaces between the textured surface, enhancing the amount of light absorbed by the material by about 90%.
Figure: Pi-Scale Consortium - Flexible OLED display
Professor Ravi Silva, Head of the Advanced Technology Institute, said, "Nature has evolved simple yet powerful adaptations, from which we have taken inspiration in order to answer challenges of future technologies."
"Moths' eyes have microscopic patterning that allows them to see in the dimmest conditions. These work by channelling light towards the middle of the eye, with the added benefit of eliminating reflections, which would otherwise alert predators of their location. We have used the same technique to make an amazingly thin, efficient, light-absorbent material by patterning graphene in a similar fashion."
Professor Silva continued, "Solar cells coated with this material would be able to harvest very dim light. Installed indoors, as part of future 'smart wallpaper' or 'smart windows', this material could generate electricity from waste light or heat, powering a numerous array of smart applications. New types of sensors and energy harvesters connected through the Internet of Things would also benefit from this type of coating."
Dr José Anguita of the University of Surrey and lead author of the paper said, "As a result of its thinness, graphene is only able to absorb a small percentage of the light that falls on it. For this reason, it is not suitable for the kinds of optoelectronic technologies our 'smart' future will demand."
Dr José Anguita added, "Nanotexturing graphene has the effect of channelling the light into the narrow spaces between nanostructures, thereby enhancing the amount of light absorbed by the material. It is now possible to observe strong light absorption from even nanometre-thin films. Typically a graphene sheet would have 2-3% light absorption. Using this method, our ultrathin coating of nanotextured few-layer graphene absorbs 95% of incident light across a broad spectrum, from the UV to the infrared."
Professor Ravi Silva noted, "The next step is to incorporate this material in a variety of existing and emerging technologies. We are very excited about the potential to exploit this material in existing optical devices for performance enhancement, whilst looking towards new applications. Through Surrey's EPSRC funded Graphene Centre, we are looking for industry partners to exploit this technology and are keen to hear from innovative companies who we can explore the future applications of this technology with us."
The Surrey team developed this technology in cooperation with BAE Systems for infrared imaging in opto-MEMs devices.
Ultra-broadband light trapping using nanotextured decoupled graphene multilayers
José V. Anguita | Muhammad Ahmad | Sajad Haq | Jeremy Allam | S. Ravi P. Silva
Science Advances 26 Feb 2016: | Vol. 2, no. 2, e1501238 | DOI: 10.1126/sciadv.1501238
The ability to engineer a thin two-dimensional surface for light trapping across an ultra-broad spectral range is central for an increasing number of applications including energy, optoelectronics, and spectroscopy. Although broadband light trapping has been obtained in tall structures of carbon nanotubes with millimeter-tall dimensions, obtaining such broadband light–trapping behavior from nanometer-scale absorbers remains elusive. We report a method for trapping the optical field coincident with few-layer decoupled graphene using field localization within a disordered distribution of subwavelength-sized nanotexturing metal particles. We show that the combination of the broadband light–coupling effect from the disordered nanotexture combined with the natural thinness and remarkably high and wavelength-independent absorption of graphene results in an ultrathin (15 nm thin) yet ultra-broadband blackbody absorber, featuring 99% absorption spanning from the mid-infrared to the ultraviolet. We demonstrate the utility of our approach to produce the blackbody absorber on delicate opto-microelectromechanical infrared emitters, using a low-temperature, noncontact fabrication method, which is also large-area compatible. This development may pave a way to new fabrication methodologies for optical devices requiring light management at the nanoscale.